SEMESTER LEARNING PLAN
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Course Title: Reaction Dynamics (DRX)
MK code: AKM21 361
Credit Weight: 2
Group of Courts: Compulsory
Semester: 6
Prerequisite Course: KD2
Lecturer:
Dra. Arnellli, MS
Yayuk Astuti, Ssi., Ph.D
Graduate Learning Outcomes (GLO)
| Attitude | GLO1-(S9) | Demonstrate an attitude of responsibility for work in their field of expertise independently. |
| Knowledge | GLO2-(PP1) | Mastering the theoretical concepts of structure, properties, changes, kinetics, and energetics of molecules and chemical systems, identification, separation, characterization, transformation, synthesis of macromolecular chemicals, and their application. |
| General Skills | GLO3-(KU1) | Able to apply logical, critical, systematic, and innovative thinking in the context of the development or implementation of science and technology that pays attention to and uses humanities values by their field of expertise |
| GLO4-(KU2) | Able to demonstrate independent, quality, and measurable performance. | |
| Special skill | GLO5-(KK2) | Able to solve science and technology problems in general chemistry and simple scopes such as identification, analysis, isolation,transformation, and synthesis of micro-molecules through the application of knowledge of the structure, properties, kinetics, and energetics of molecules and chemical systems, with analysis and synthesis methods in specific chemical fields, as well as the application of relevant technologies |
Course Learning Outcomes (CLO)
| CLO-1 | Students can apply the integrated rate law to determine the rate law for complex reactions, including irreversible reactions,reversible, parallel, sequential, autocatalyst, Sn1 and Sn2 |
| CLO-2 | Students can explain the occurrence of reactions according to collision theory and transition state theory, as well as the parameters that influence |
| CLO-3 | Students can explain the role of the solvent on the reaction rate and the factors that affect the reaction in the solution |
| CLO-4 | Students can explain the mechanism of homogeneous catalytic reactions, including acid-base catalysis, enzymes, and electron transfer, and determine the reaction rate |
| CLO-5 | Students can explain the growth process on the surface and be able to distinguish between physisorption and chemisorption, as well as the stages of chemical reactions on the solid surface |
| CLO-6 | Students can explain the rate of adsorption and desorption of the type of molecularity absorbed |
| CLO-7 | Students can explain the mechanism of heterogeneous catalysis, the relationship between catalyst activity and reaction rate |
| CLO-8 | Students can explain the basic laws of reactions that occur due to absorption of light radiation such as photosynthesis, fluorescence, and phosphorescence and determine the rate of the reaction |
Course Description
This course examines kinetics at the unimolecular, bimolecular, and thermomolecular levels based on collision theory and absolute velocity in gas systems. Based on this theory, it will be applied to calculate reaction kinetics in reactions in solution, reactions on the surface of solids and the factors that influence them, and reactions that occur due to the absorption of ultraviolet and visible light radiation.
| Week | Expected ability (Sub-CLO) | Study Materials/ Learning Materials | Learning methods | Student Learning Experience | Time (minutes) | Evaluation | |
| Criteria and Indicators | % | ||||||
| 1-2 | Students can apply the integrated rate law to determine the rate law for complex reactions, whether irreversible, reversible, parallel, sequential, autocatalytic, and Sn1 and Sn2. | BK3. KINETIC CONCEPT
PB1. Law of Rate integrated for complex reactions. a. irreversible reaction b. Reversible reaction c. Parallel and sequential reactions d. Autocatalyst reaction and Sn1 and Sn2 reaction |
Discovery learning
Cooperative learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) – Searching, collecting, and compiling existing information to describe knowledge of the rate law of complex reactions, including irreversible, reversible, parallel, sequential, autocatalyst reactions and Sn1 and Sn2 reactions – Discuss and conclude the problems/tasks given by the lecturer in groups. |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– the accuracy of determining the rate equation for complex reactions
– accuracy in using complex reaction rate equations to solve given problems |
10 |
| 3-4 | Students can explain the occurrence of reactions according to collision theory and transition state theory, as well as the parameters that influence | BK3. KINETIC CONCEPT
PB2. Collision theory and Transition state theory a. Collision Rate b. Energy and steric needed c. Thermodynamic aspects d. kinetic isotope effect |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) – Discuss and conclude the problems/tasks given by the lecturer in groups. |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– Accuracy in explaining the occurrence of reactions in terms of collision theory and transition state theory and determining the collision rate equation
– the accuracy of using the formulas in collision theory and transition state theory to solve the given problems |
10 |
| 5 | Students can explain the role of the solvent on the reaction rate and the factors that affect the reaction in the
solution |
BK3. KINETIC CONCEPT
PB3. Reaction in solution a. The role of the solvent on the reaction rate b. Reaction between ions in solution c. Reaction between ion-dipole and dipole-dipole |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– accurately describes the role of the solvent on the reaction rate in the solution reaction and the influencing parameters such as dielectric constant, ionic strength, etc.
– the accuracy of using the formulas in the factors that affect the reaction rate on the reaction of the solution in solving the problems given |
15 |
| 6-7 | Students can explain the mechanism of homogeneous catalytic reactions, including acid-base catalysts, enzymes, electron transfer, and determine the reaction rate | BK3. KINETIC CONCEPT
PB4. Homogeneous catalyst a. Mechanism and rate of catalytic reaction b. Acid-base catalyst c. Enzyme catalyst d. Electron transfer catalyst |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– Accuracy in explaining the mechanism of homogeneous catalysis reactions, which include acid-base catalysts, enzymes, electron transfer, and reaction rates
– the accuracy of using the rate equation of a reaction in homogeneous catalysis to solve the given problems |
15 |
| 8 | Midterm exam | Written exam | 90 | Truth in solving exam questions | |||
| 9 | Students can explain the growth process on the surface and be able to distinguish between physisorption and chemisorption, as well as the stages of chemical reactions on the solid surface | BK3. KINETIC CONCEPT
PB5. Introduction to solid surfaces a. Surface growth b. Physisorption and chemisorption c. Mechanism of reaction on solid surface |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) Discuss and conclude the problems/tasks given by the lecturer in groups. Discuss and conclude the problems/tasks given by the lecturer in groups. |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– Accuracy in explaining the growth process on the surface, distinguishing between physisorption and chemisorption, and the stages of chemical reactions occurring on the solid surface
– the accuracy of using the formulas in determining the rate of physisorption and chemisorption reactions to solve the given problems |
5 |
| 10 | Students can explain the adsorption rate of the type of molecularity that is absorbed using the Isotherm adsorption approach | BK3. KINETIC CONCEPT
PB6. Adsorption and desorption a. Adsorption isotherm |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) – communication and cooperation |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– the accuracy of explaining the rate of the adsorption reaction with the adsorption isotherm approach
– the accuracy of using the formulas in the adsorption isotherm to solve the problems given |
10 |
| 11 | students can explain the rate of adsorption and desorption from the type of molecularity | BK3. KINETIC CONCEPT
PB6. Adsorption and desorption b. Adsorption and desorption rate |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– the accuracy of explaining the adsorption and desorption rate equations of the type of molecularity
– the accuracy of using the adsorption and desorption rate formulas to solve the given problems |
15 |
| 12-13 | students can explain the mechanism of heterogeneous catalysis and the relationship between catalyst activity and reaction rate | BK3. KINETIC CONCEPT
PB7. Heterogeneous catalyst a. Heterogeneous catalysis mechanism b. Catalyst activity on the surface |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) searching, collecting, and compiling existing information to describe knowledge. |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– Accuracy in explaining the mechanism of heterogeneous catalysis and determining the rate equation for the reaction
– the accuracy of using the reaction rate formulas in heterogeneous catalysis to solve the given problems |
10 |
| 14-15 | Students can explain the basic laws of reactions that occur due to absorption of light radiation such as photosynthesis, fluorescence, and phosphorescence and determine the reaction rates of several photochemical reactions | BK3. KINETIC CONCEPT
PB8. Photochemistry a. Photochemical process b. Photochemical rate law |
Discovery learning
Cooperative learning Problem Based Learning |
– Summarizing the material presented by the lecturer
– Asking (development, criticism) – Communication, cooperation, mutual respect – Searching, collecting and compiling existing information to describe a knowledge |
FF: 2 x 50
ST: 2 x 60 SS: 2 x 60 |
– Accuracy in explaining the basic laws of photochemical reactions and their rate equations
– the accuracy of using the reaction rate equations of several photochemical reactions to solve the given problems |
10 |
| 16 | Final exams | Written exam | 90 | The truth and completeness of the answer to the question | |||
| Total Rating | 100 | ||||||
Reference:
- Peter Atkinsa and Julio de Paula, 2014, Arkins’ Physical Chemistry, 10th Edition, Oxford: UK
- K. J. Laidler, Chemical Kinetics, New York, Harper Collins Publisher
- Wilkinsons, 1980, Chemical Kinetics and Reaction Mechanism, Amsterdam, van nastrand.
- E. Caliskan S. & S. Gokturk, Adsorption characteristics of sulfamethoxazole and metronidazole on activated carbon, Separation science and technology, 2010, 45: 244-255
- E. Caliskan S., J. Wang, D. J. L. Coleman & l. Siller, Enhanced removal of nickel (II) ions from aqueous solutions by SDS-functionalized graphene oxide, Separation science and technology, 2016
- E. C. Salihi & M. Mahramanliohlu, Equilibrium and kinetics adsorption of drugs on bentonite: presence of surface active agents effect, Applied clay science, 2014
- M. N. Rashed & A. A. El-Amin, Photocatalytic degradation of methyl orange in aqueous TiO2 under different solar irradiation sources, International Journal of Physical Sciences, 2007, 2: 073-081
Glossary
GLO = Graduate Learning Outcome
CLO = Course Learning Outcomes
FF = Face to Face Learning
ST = Structured tasks
SS = Self Study
