SEMESTER LEARNING PLAN
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Course Title: Inorganic Chemistry 4 (KAno4)
MK code: AKM21 353
Credit Weight: 3
Group of Courts: Compulsory
Semester: 5
Prerequisite Course: KAno3
Lecturer:
Dra. Sriyanti, M.Si
Drs. Suhartana, M.Si.
Sriatun, S.Si., M.Si.
Graduate Learning Outcomes (GLO)
| Attitude | GLO1-(S9) | Demonstrate an attitude of responsibility for work in their field of expertise independently. |
| Knowledge | GLO2-(PP1) | Mastering the theoretical concepts of structure, properties, changes, kinetics, and energetics of molecules and chemical systems, identification, separation, characterization, transformation, synthesis of macromolecular chemicals, and their application. |
| GLO3-(PP3) | Mastering the basic principles of software for analysis, synthesis, and molecular modeling in general or more specific chemical fields. | |
| General Skills | GLO4-(KU1) | Able to apply logical, critical, systematic, and innovative thinking in the context of the development or implementation of science and technology that pays attention to and uses humanities values by their field of expertise |
| Special Skills | GLO5-(KK3) | Able to analyze several alternative solutions in the field of identification and analysis of simple solids |
Course Description
In this course, students learn about the application and expansion of coordination compounds, including understanding and basics of reactions for the formation of organometallic compounds, characterization of organometallic compounds, reactions, and catalysis that can occur in organometallic compounds
| Week | Expected ability (Sub-CLO) | Study Materials/ Learning Materials | Learning methods | Student Learning Experience | Time (minutes) | Evaluation | |
| Criteria and Indicators | % | ||||||
| 1 | Able to understand (C2), construct (P4), and discuss (A2) Definition, history of organometallic and organic ligands and their nomenclature | Inter-Molecular Interaction/ Introduction to Organometallic Chemistry (PB1)
a. Definition and History of Organometal b. Organic ligands and their nomenclature |
Discovery learning
Cooperative learning |
Summarizing information, asking (development, criticism), searching, gathering, and compiling existing information to describe knowledge about the origin of organometallic chemistry
Discuss and conclude the problems/tasks given by the lecturer in groups. |
FF: 1 x (3 x 50”)
ST + SS: 1 x [(3 x 50”) + (3 x 60”)] |
Accuracy in explaining the basis of organometallic compounds, understanding, and nomenclature of organic ligands
>>> with a minimum accuracy of 80% |
5 |
| 2 | Able to understand (C2), construct (P4), and discuss (A2) the 18 electron rule | Molecular Structure/ 18 electron rule (PB2)
a. Electron Count b. Why 18 electrons? c. Planar quadrangular complex |
Discovery learning
Cooperative learning |
Summarizing information, asking (development, critique)
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 1 x (3 x 50”)
ST + SS: 1 x [(3 x 50”) + (3 x 60”)] |
Accuracy explains the 18-electron rule as a basic concept in organometallic
>>> with a minimum accuracy of 80% |
10 |
| 3 | Able to understand (C2), construct (P4), and discuss (A2) ligands in organometallic chemistry | Inter-Molecular/Ligan Interactions in Organometallic Chemistry (PB3)
a. Carbonyl Complex (CO) b. similarity ligands CO |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer
|
FF: 1 x (3 x 50”)
ST + SS: 1 x [(3 x 50”) + (3 x 60”)] |
Accuracy of describing the carbonyl complex (CO)
Accuracy of describing similarity ligands CO |
5 |
| 4 | Able to understand (C2), construct (P4), and discuss (A2) ligands in organometallic chemistry | Inter-Molecular/Ligan Interactions in Organometallic Chemistry (PB3)
c. Dihydrogen complex d. Ligands that have an extension of the Pi system |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy of explaining about hydrogen complex
Accuracy in describing ligands that have an extension of the Pi system |
5 |
| 5 | Able to understand (C2), construct (P4), and discuss (A2) Bonds between Metal Atoms and the Organic Pi system | Inter-Molecular/Bonding Interactions between Metal Atoms and the Organic Pi system (PB4)
a. Linear Pi System b. Cyclic Pi System |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy describes the linear pi system in the bond between metal atoms and the organic pi system.
Accuracy describes the cyclic pic system in the bond between metal atoms and the organic pi system. |
10 |
| 6 | Able to understand (C2), construct (P4), and discuss (A2) Complexes containing metal-carbon sigma bonds | Inter-Molecular/Complex Interactions Containing Metal-Carbon (PB5) Sigma Bonds
a. Alkyl Complex b. Carbene Complex (Alkylidene) c. Carbyne Complex (Alkylidyne) |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking questions, learning by digging/looking for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer | FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
the accuracy of describing alkyl complexes
accurate description of carbene (alkylidene) complexes |
5 |
| 7 | Able to apply (C3), construct (P4), and discuss (A2) the characterization of organometallic complexes | Qualitative Analysis/Characterization of Organometallic Complexes (PB6)
a. IR spectra b. NMR spectra c. Examples of Organometallic Characterization |
Problem Based Learning | listen, write, ask
learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy of explaining IR spectra
Accuracy explains about NMR spectra |
10 |
| 8 | Midterm exam | Written exam | 90 | Truth in solving exam questions | |||
| 9 | Able to understand (C2), construct (P4), and discuss (A2) Reactions involving addition or subtraction of ligands | Compound Reactions/Reactions involving addition or subtraction of ligands (PB7)
a. Ligand dissociation and substitution b. Oxidative Addition Reaction |
Discovery learning
Cooperative learning Problem Based Learning |
listen, write, ask
learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
accurately describes the dissociation and substitution of ligands
accurately describes the oxidative addition reaction |
10 |
| 10 | Able to understand (C2), construct (P4), and discuss (A2) Reactions involving addition or subtraction of ligands | Compound Reactions/Reactions involving addition or subtraction of ligands (PB7)
c. Reductive Elimination d. Sigma Bond Metathesis |
Discovery learning
Cooperative learning Problem Based Learning |
listen, write, ask
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy explains about reductive elimination
the accuracy of explaining the metathesis of sigma bonds |
5 |
| 11 | Able to understand (C2), construct (P4), and discuss (A2) Reactions involving ligand modification | Compound Reactions/Reactions involving ligand modification (PB8)
a. Insertion Reaction b. Carbonyl Insertion Reaction (Alkyl migration) c. 1,2 insertion examples |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy describes the insertion reaction.
Accuracy describes the carbonyl insertion reaction (alkyl migration) |
10 |
| 12 | Able to understand (C2), construct (P4), and discuss (A2) Reactions involving ligand modification | Compound Reactions /Reactions involving ligand modification (PB8)
d. Hydride Elimination Reaction e. Abstraction |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy describes the hydride elimination reaction
Accuracy explains abstraction |
5 |
| 13 | Able to understand (C2), construct (P4), and discuss (A2) Organometallic Catalysts | Concept of Organometallic Catalyst/catalyst (PB9)
a. Deuteration Catalytic b. hydroformylation c. Monsanto Process Acetic Acid |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy in explaining about Deuteration catalytic
Accuracy explains hydroformylation Accurately explain the Monsanto Acetic Acid process. |
5 |
| 14 | Able to understand (C2), construct (P4), and discuss (A2) Organometallic Catalysts | Concept of Organometallic Catalyst/catalyst (PB9)
d. Wacker Process (Smitdt) e. Hydrogenation with Wilkinson catalyst f. Olefin Metathesis |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy describes the Wacker Process (Smitdt)
Accuracy in explaining hydrogenation with Wilkinson catalyst Accuracy explains about Olefin meta metathesis |
5 |
| 15 | Able to understand (C2), construct (P4), and discuss (A2) Heterogeneous Catalyst | Concept of Catalyst/ Heterogeneous Catalyst (PB10)
a. Ziegler-Natta Poli polymerization b. Water-Gas Reaction |
Discovery learning
Cooperative learning Problem Based Learning |
Listening, writing, asking
Learn by digging/searching for information (inquiry) and utilizing that information to solve factual problems/designed by the lecturer |
FF: 3 x 50
ST: 3 x 60 SS: 3 x 60 |
Accuracy explains about Ziegler-Natta Poli Polymerization
Accuracy in describing the Water-Gas Reaction |
10 |
| 16 | Final exams | Written exam | 90 | The truth and completeness of the answer to the question | |||
| Total Rating | 100 | ||||||
Reference:
- Garry L. Miesler, Donald A Tarr, 2014, “Inorganic Chemistry”, Prentice Hall International Edition, Singapore
- Crabtree, R.H., 1988, “The Organometallic Chemistry of The Transition Metals,” John Wiley and Sons, New York
Glossary
GLO = Graduate Learning Outcome
CLO = Course Learning Outcomes
FF = Face to Face Learning
ST = Structured tasks
SS = Self Study
